Lecture Notes

Lec # TOPICS
1-4 Experimental Evidence for Quantum Mechanics (PDF)

Polarization of Light

Single Molecule Fluorescence
5-7 The Machinery of Quantum Mechanics (This resource may not render correctly in a screen reader.PDF)

Hilbert Space

State Vectors

Bra-Ket

Operators and Eigenvalues
8-12 Exactly Solvable Problems (This resource may not render correctly in a screen reader.PDF)

Operators and States in Real Space

Harmonic Oscillator

Position Representation and Wave Mechanics

Piecewise Constant Potentials
13-15 Matrix Mechanics (PDF)

Vector Representation of States

Matrices as Operators

Interesting Matrix Properties

Discrete Variable Representation

Variational Method
16-18 Time Dependence (PDF)

Energy Eigenstates and Stationary States

The Propagator

Time Dependence of Average Values

Matrix Representations of the Propagator

Example: Inversion of the Ammonia Molecule
19-20 Angular Momentum (PDF)

Rotations

Commutation Relations

Eigenstates
21-22 Central Potentials (This resource may not render correctly in a screen reader.PDF)

Spherical Polar Coordinates

Orbital Angular Momentum Operators

Spherical Harmonics

The Radial Equation

Hydrogen-like Atoms

Electron Spin
23-24 Addition of Angular Momenta (This resource may not render correctly in a screen reader.PDF)

Coupled and Uncoupled Bases

Recursion Relations

The Triangle Rule
25 Wigner-Eckart Theorem (PDF)

Spherical Tensors
26-28 Perturbation Theory (This resource may not render correctly in a screen reader.PDF)
29-31 Identical Particles (This resource may not render correctly in a screen reader.PDF)

The Product Basis

Symmetry Under Exchange

Two Electron Atoms

Hartree-Fock

Perturbation Theory

Configuration Interaction
32-34 The Born-Oppenheimer Approximation (This resource may not render correctly in a screen reader.PDF)

The Adiabatic Approximation

The Coupled Channel Hamiltonian

Non-Adiabatic Effects

Diabatic States

Electron Transfer
35-38 The Hydrogen Molecule (This resource may not render correctly in a screen reader.PDF)

Minimal Atomic Orbital Basis

Molecular Orbital Picture

Valence Bond Picture